Synthesis, Structure and Norbornene Polymerization Catalyzed by o-Benzene Diimine Di-nuclear Palladium(Ⅱ) Complex

Citation: LI Chao, LAN Mei-Ying, MENG Su-Qin, CHEN Jian-Xin, ZHANG Zhi-Chun. Synthesis, Structure and Norbornene Polymerization Catalyzed by o-Benzene Diimine Di-nuclear Palladium(Ⅱ) Complex[J]. Chinese Journal of Structural Chemistry, 2014, 33(4): 607-611. shu

Synthesis, Structure and Norbornene Polymerization Catalyzed by o-Benzene Diimine Di-nuclear Palladium(Ⅱ) Complex

a.
a. College of Chemistry and Chemical Engineering, Fujian Normal University, Fuzhou 350007, China;
b.
b. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

通讯作者: CHEN Jian-Xin,

基金项目:
This work was supported by the Natural Science Foundation of Fujian Province (2010J01026) (2010J01026)

the Ministry of Education of China (No.208066) (No.208066)

the Education Department of Fujian Province (JA07029) (JA07029)

the State Key Laboratory of Structural Chemistry (No. 20130013) (No. 20130013)

摘要: The title complex, C₂₀H₁₇N₄Pd₂Cl₃·0.5CH₃OH, crystallizes in the triclinic system, space group P1 with a=9.927(6), b=11.079(6), c=11.233(6) Å, α=73.970(12), β=85.738(16), γ=83.300(12)°, V=1178.1(11) Å³, M_r=648.55, Z=2, D_c=1.520 g/cm³, μ=1.884 mm^-1, F(000)=634, the final R=0.0460 and wR=0.1280. This title compound was investigated for the catalytic behavior towards norbornene (NB) vinyl addition polymerization. And the complex exhibits good catalytic activity to catalyze norbornene polymerization using MAO as a cocatalyst.

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