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负载型Ni-Co-P/CNFs催化剂的制备及释氢性能

李忠 ,  王丽娜 ,  王桂雪 ,  谢广文

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引用本文: 李忠, 王丽娜, 王桂雪, 谢广文. 负载型Ni-Co-P/CNFs催化剂的制备及释氢性能[J]. 燃料化学学报, 2015, 43(3): 372-378. shu
Citation:  LI Zhong, WANG Li-na, WANG Gui-xue, XIE Guang-wen. Hydrogen generation from the hydrolysis of sodium borohydride solution over the supported Ni-Co-P/CNFs catalysts[J]. Journal of Fuel Chemistry and Technology, 2015, 43(3): 372-378. shu

负载型Ni-Co-P/CNFs催化剂的制备及释氢性能

    通讯作者: 谢广文,Tel:0532-84022883;E-mail:xiegw@qust.edu.cn。
  • 基金项目:

    山东省自然科学基金(ZR2011EMM005)。 (ZR2011EMM005)

摘要: 以纳米碳纤维(CNFs)为基体材料,采用化学镀法在CNFs表面沉积了Ni-Co-P催化剂。研究了催化剂用量,硼氢化钠、氢氧化钠浓度,温度等对碱性硼氢化钠溶液水解释氢的影响。电感耦合等离子体原子发射光谱法(ICP-AES)测试得出负载型Ni-Co-P催化剂含镍13.30%(质量分数,下同)、钴82.25%、磷4.45%。硼氢化钠水解释氢实验结果表明,产氢速率与催化剂用量呈线性关系。当温度为45 ℃、催化剂浓度为7.5 g/L、氢氧化钠浓度为5%、硼氢化钠浓度为2.5%时,氢气释放速率达到最大值18.044 L/(g·min)。通过对负载型催化剂Ni-Co-P/CNFs催化碱性硼氢化钠溶液释放氢气动力学研究表明,该催化剂的活化能Ea为51.57 kJ/mol。

English

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