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减压蒸馏生物油与乙醇在ZSM-5/MCM-41上共催化裂化

李美惠 ,  马文超 ,  毕亚东 ,  陈冠益 ,  陈慧

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引用本文: 李美惠, 马文超, 毕亚东, 陈冠益, 陈慧. 减压蒸馏生物油与乙醇在ZSM-5/MCM-41上共催化裂化[J]. 燃料化学学报, 2015, 43(3): 309-314. shu
Citation:  LI Mei-hui, MA Wen-chao, BI Ya-dong, CHEN Guan-yi, CHEN Hui. Catalytic co-cracking of reduced pressure distillation of bio-oil and ethanol over ZSM-5/MCM-41[J]. Journal of Fuel Chemistry and Technology, 2015, 43(3): 309-314. shu

减压蒸馏生物油与乙醇在ZSM-5/MCM-41上共催化裂化

    通讯作者: 马文超,博士,Tel:18602272358,E-mail:mawc916@tju.edu.cn。
  • 基金项目:

    国家自然科学基金(51036006, 51306131)。 (51036006, 51306131)

摘要: 采用减压蒸馏生物油为原料,与无水乙醇2:3(质量比)混合,在固定床中ZSM-5/MCM-41分子筛上共催化裂化,考查了反应温度和质量空速(WHSV)对裂化产物的影响。对ZSM-5/MCM-41进行了NH3-TPD、BET、N2吸附-脱附等表征,对裂化气体产物通过气相色谱仪分析,减压蒸馏生物油和精制生物油采用气相色谱-质谱联用仪进行定量分析。结果表明,反应温度500 ℃、WHSV 3.75 h-1为反应优化工况。此反应条件下,精制生物油酸类物质从减压蒸馏生物油中的25.6%降至反应后的0.1%,效果显著,且精制生物油产率为46.8%,气体产物中CO2和CO的浓度共9.5%。

English

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    1. [1] 杨中志. 木屑加压液化与液体产物分级制备燃料油过程研究[D]. 北京: 中国林业科学研究院, 2013.(YANG Zhong-zhi. Liquefication of sawdust and separation processing of liquefied products for the production of bio-fuels[D]. Beijing: Chinese Academy of Forestry, 2013.)[1] 杨中志. 木屑加压液化与液体产物分级制备燃料油过程研究[D]. 北京: 中国林业科学研究院, 2013.(YANG Zhong-zhi. Liquefication of sawdust and separation processing of liquefied products for the production of bio-fuels[D]. Beijing: Chinese Academy of Forestry, 2013.)

    2. [2] 李美莲, 柏雪源, 李永军, 高晓凤. 生物质热解气中固体颗粒的分离方法综述[J]. 生物质化学工程, 2012, 46(3): 49-55.(LI Mei-lian, BAI Xue-yuan, LI Yong-jun, GAO Xiao-feng. The separation methods of solid particles in biomass pyrolysis gas[J]. Biomass Chem Eng, 2012, 46(3): 49-55.)[2] 李美莲, 柏雪源, 李永军, 高晓凤. 生物质热解气中固体颗粒的分离方法综述[J]. 生物质化学工程, 2012, 46(3): 49-55.(LI Mei-lian, BAI Xue-yuan, LI Yong-jun, GAO Xiao-feng. The separation methods of solid particles in biomass pyrolysis gas[J]. Biomass Chem Eng, 2012, 46(3): 49-55.)

    3. [3] 黄晓露. 木质素模型化合物热解的微观机理研究[D]. 重庆: 重庆大学, 2012.(HUANG Xiao-lu. Studies of molecular level pyrolysis mechanism of lignin model compounds[D]. Chongqing: Chongqing University, 2012.)[3] 黄晓露. 木质素模型化合物热解的微观机理研究[D]. 重庆: 重庆大学, 2012.(HUANG Xiao-lu. Studies of molecular level pyrolysis mechanism of lignin model compounds[D]. Chongqing: Chongqing University, 2012.)

    4. [4] ZHOU L Y, YANG H M, WU H, WANG M, CHENG D Q. Catalytic pyrolysis of rice husk by mixing with zincoxide: Characterization of bio-oil and its rheological behavior[J]. Fuel Process Technol, 2013, 106(2): 385-391.[4] ZHOU L Y, YANG H M, WU H, WANG M, CHENG D Q. Catalytic pyrolysis of rice husk by mixing with zincoxide: Characterization of bio-oil and its rheological behavior[J]. Fuel Process Technol, 2013, 106(2): 385-391.

    5. [5] 姜小祥, Naoko Ellis, 仲兆平. 生物油/生物柴油乳化燃料的制备及性质分析[J]. 东南大学学报: 自然科学版, 2010, 40(4): 789-793.(JIANG Xiao-xiang, Naoko Ellis, ZHONG Zhao-ping. Preparing emulsion of bio-oil/bio-diesel and properties analysis[J]. J Southeast Univ (Nat Sci Ed), 2010, 40(4): 789-793.)[5] 姜小祥, Naoko Ellis, 仲兆平. 生物油/生物柴油乳化燃料的制备及性质分析[J]. 东南大学学报: 自然科学版, 2010, 40(4): 789-793.(JIANG Xiao-xiang, Naoko Ellis, ZHONG Zhao-ping. Preparing emulsion of bio-oil/bio-diesel and properties analysis[J]. J Southeast Univ (Nat Sci Ed), 2010, 40(4): 789-793.)

    6. [6] 王树荣, 蔡勤杰, 王相宇, 张力, 王誉蓉, 骆仲泱. 生物油酸酮类模化物与乙醇在 HZSM-5 上共裂化制备生物汽油[J]. 催化学报, 2014, 35(5): 709-722.(WANG Shu-rong, CAI Qin-jie, WANG Xiang-yu, ZHANG Li, WANG Yu-rong, LUO Zhong-yang. Biogasoline production by co-cracking of model compound mixture of bio-oil and ethanol over HZSM-5[J]. Chin J Catal, 2014, 35(5): 709-722.)[6] 王树荣, 蔡勤杰, 王相宇, 张力, 王誉蓉, 骆仲泱. 生物油酸酮类模化物与乙醇在 HZSM-5 上共裂化制备生物汽油[J]. 催化学报, 2014, 35(5): 709-722.(WANG Shu-rong, CAI Qin-jie, WANG Xiang-yu, ZHANG Li, WANG Yu-rong, LUO Zhong-yang. Biogasoline production by co-cracking of model compound mixture of bio-oil and ethanol over HZSM-5[J]. Chin J Catal, 2014, 35(5): 709-722.)

    7. [7] 朱锡锋. 生物质热解液化技术研究与发展趋势[J]. 新能源进展, 2013, 1(1): 32-37.(ZHU Xi-feng. Research development of biomass fast pyrolysis[J]. Adv New Renew Energy, 2013, 1(1): 32-37.)[7] 朱锡锋. 生物质热解液化技术研究与发展趋势[J]. 新能源进展, 2013, 1(1): 32-37.(ZHU Xi-feng. Research development of biomass fast pyrolysis[J]. Adv New Renew Energy, 2013, 1(1): 32-37.)

    8. [8] 马文超, 陈娇娇, 王铁军, 陈冠益, 马隆龙, 张琦. 生物油模型化合物催化裂解机理[J]. 农业工程学报, 2013, 29(9): 207-213.(MA Wen-chao, CHEN Jiao-jiao, WANG Tie-jun, CHEN Guan-yi, MA Long-long, ZHANG Qi. Catalytic cracking mechanism of bio-oil model compounds[J]. Trans Chin Soc Agric Eng, 2013, 29(9): 207-213.)[8] 马文超, 陈娇娇, 王铁军, 陈冠益, 马隆龙, 张琦. 生物油模型化合物催化裂解机理[J]. 农业工程学报, 2013, 29(9): 207-213.(MA Wen-chao, CHEN Jiao-jiao, WANG Tie-jun, CHEN Guan-yi, MA Long-long, ZHANG Qi. Catalytic cracking mechanism of bio-oil model compounds[J]. Trans Chin Soc Agric Eng, 2013, 29(9): 207-213.)

    9. [9] 陈娇娇, 陈冠益, 马文超, 马隆龙, 王铁军, 张琦, 吕微. 生物油模型化合物催化裂化制备芳香烃的实验研究[J]. 燃料化学学报, 2013, 41(2): 183-188.(CHEN Jiao-jiao, CHEN Guan-yi, MA Wen-chao, MA Long-long, WANG Tie-jun, ZHANG Qi, LÜ Wei. Experimental study of aromatics production from catalytic cracking of bio-oil model compounds[J]. J Fuel Chem Technol, 2013, 41(2): 183-188.)[9] 陈娇娇, 陈冠益, 马文超, 马隆龙, 王铁军, 张琦, 吕微. 生物油模型化合物催化裂化制备芳香烃的实验研究[J]. 燃料化学学报, 2013, 41(2): 183-188.(CHEN Jiao-jiao, CHEN Guan-yi, MA Wen-chao, MA Long-long, WANG Tie-jun, ZHANG Qi, LÜ Wei. Experimental study of aromatics production from catalytic cracking of bio-oil model compounds[J]. J Fuel Chem Technol, 2013, 41(2): 183-188.)

    10. [10] 马燕辉, 赵会玲, 唐圣杰, 胡军, 刘洪来. 微孔/介孔复合分子筛的合成及其对CO2的吸附性能[J]. 物理化学学报, 2011, 27(3): 689-696.(MA Yan-hui, ZHAO Hui-ling, TANG Sheng-jie, LIU Hong-lai. Synthesis of micro/mesoporous composites and their application as CO2 adsorbents[J]. Acta Phys-Chim Sin, 2011, 27(3): 689-696.)[10] 马燕辉, 赵会玲, 唐圣杰, 胡军, 刘洪来. 微孔/介孔复合分子筛的合成及其对CO2的吸附性能[J]. 物理化学学报, 2011, 27(3): 689-696.(MA Yan-hui, ZHAO Hui-ling, TANG Sheng-jie, LIU Hong-lai. Synthesis of micro/mesoporous composites and their application as CO2 adsorbents[J]. Acta Phys-Chim Sin, 2011, 27(3): 689-696.)

    11. [11] 赵彬, 王向宇. 用于氧化反应的改性介孔分子筛 MCM-41 研究进展[J]. 工业催化, 2013, 21(1): 1-5.(ZHAO Bin, WANG Xiang-yu. Advances in modification of mesoporous molecular sieve MCM-41 for oxidation reaction[J]. Ind Catal, 2013, 21(1): 1-5.)[11] 赵彬, 王向宇. 用于氧化反应的改性介孔分子筛 MCM-41 研究进展[J]. 工业催化, 2013, 21(1): 1-5.(ZHAO Bin, WANG Xiang-yu. Advances in modification of mesoporous molecular sieve MCM-41 for oxidation reaction[J]. Ind Catal, 2013, 21(1): 1-5.)

    12. [12] 韩伟, 贾玉心, 熊国兴, 杨维慎. 介孔-微孔复合材料的水热稳定性及其催化裂化性能[J]. 催化学报, 2011, 32(3): 418-427.(HAN Wei, JIA Yu-xin, XIONG Guo-xing, YANG Wei-shen. Hydrothermal stability of meso-microporous composites and their catalytic cracking performance[J]. Chin J Catal, 2011, 32(3): 418-427.)[12] 韩伟, 贾玉心, 熊国兴, 杨维慎. 介孔-微孔复合材料的水热稳定性及其催化裂化性能[J]. 催化学报, 2011, 32(3): 418-427.(HAN Wei, JIA Yu-xin, XIONG Guo-xing, YANG Wei-shen. Hydrothermal stability of meso-microporous composites and their catalytic cracking performance[J]. Chin J Catal, 2011, 32(3): 418-427.)

    13. [13] MORTENSEN P M, GRUNWALDT J D, JENSEN P A, KNUDSEN K G, JENSEN A D. A review of catalytic upgrading of bio-oil to engine fuels[J]. Appl Catal A: Gen, 2011, 407(1): 1-19.[13] MORTENSEN P M, GRUNWALDT J D, JENSEN P A, KNUDSEN K G, JENSEN A D. A review of catalytic upgrading of bio-oil to engine fuels[J]. Appl Catal A: Gen, 2011, 407(1): 1-19.

    14. [14] MENTZEL U V, HOLM M S. Utilization of biomass: Conversion of model compounds to hydrocarbons over zeolite H-ZSM-5[J]. Appl Catal A: Gen, 2011, 396(1): 59-67.[14] MENTZEL U V, HOLM M S. Utilization of biomass: Conversion of model compounds to hydrocarbons over zeolite H-ZSM-5[J]. Appl Catal A: Gen, 2011, 396(1): 59-67.

    15. [15] CHEN G Y, LIU C, MA W C, ZHANG X X, LI Y B, YAN B B, ZHOU W H. Co-pyrolysis of corn cob and waste cooking oil in a fixed bed[J]. Bioresour Technol, 2014, 166(8): 500-507.[15] CHEN G Y, LIU C, MA W C, ZHANG X X, LI Y B, YAN B B, ZHOU W H. Co-pyrolysis of corn cob and waste cooking oil in a fixed bed[J]. Bioresour Technol, 2014, 166(8): 500-507.

    16. [16] WANG S R, CAI Q J, WANG X Y, GUO Z G, LUO Z Y. Bio-gasoline production from co-cracking of hydroxypropanone and ethanol[J]. Fuel Process Technol, 2013, 111(7): 86-93.[16] WANG S R, CAI Q J, WANG X Y, GUO Z G, LUO Z Y. Bio-gasoline production from co-cracking of hydroxypropanone and ethanol[J]. Fuel Process Technol, 2013, 111(7): 86-93.

    17. [17] 王娜. 生物质热解炭, 气, 油联产实验研究[D]. 天津: 天津大学, 2012.(WANG Na. The experimental study on production of charcoal, bio-gas and bio-oil from biomass pyrolysis[D]. Tianjin: Tianjin University, 2012.)[17] 王娜. 生物质热解炭, 气, 油联产实验研究[D]. 天津: 天津大学, 2012.(WANG Na. The experimental study on production of charcoal, bio-gas and bio-oil from biomass pyrolysis[D]. Tianjin: Tianjin University, 2012.)

    18. [18] CHATTANATHAN A S, ADHIKARI S, ABDOULMOUMINE N. A review on current status of hydrogen production from bio-oil[J]. Renew Sust Energy Rev, 2012, 16(5): 2366-2372.[18] CHATTANATHAN A S, ADHIKARI S, ABDOULMOUMINE N. A review on current status of hydrogen production from bio-oil[J]. Renew Sust Energy Rev, 2012, 16(5): 2366-2372.

    19. [19] ABU BAKAR M S, TITILOYE J O. Catalytic pyrolysis of rice husk for bio-oil production[J]. J Anal Appl Pyrolysis, 2013, 103(9): 362-368.[19] ABU BAKAR M S, TITILOYE J O. Catalytic pyrolysis of rice husk for bio-oil production[J]. J Anal Appl Pyrolysis, 2013, 103(9): 362-368.

    20. [20] WANG S R, GUO Z G, CAI Q J, GUO L. Catalytic conversion of carboxylic acids in bio-oil for liquid hydrocarbons production[J]. Biomass Bioenergy, 2012, 45(10): 138-143.[20] WANG S R, GUO Z G, CAI Q J, GUO L. Catalytic conversion of carboxylic acids in bio-oil for liquid hydrocarbons production[J]. Biomass Bioenergy, 2012, 45(10): 138-143.

    21. [21] 王树荣, 廖艳芬, 刘倩, 骆仲泱, 岑可法. 酸洗预处理对纤维素热裂解的影响研究[J]. 燃料化学学报, 2006, 34(2): 179-183.(WANG Shu-rong, LIAO Yan-fen, LIU Qian, LUO Zhong-yang, CEN Ke-fa. Experimental study of the influence of acid wash on cellulose pyrolysis[J]. J Fuel Chem Technol, 2006, 34(2): 179-183.)[21] 王树荣, 廖艳芬, 刘倩, 骆仲泱, 岑可法. 酸洗预处理对纤维素热裂解的影响研究[J]. 燃料化学学报, 2006, 34(2): 179-183.(WANG Shu-rong, LIAO Yan-fen, LIU Qian, LUO Zhong-yang, CEN Ke-fa. Experimental study of the influence of acid wash on cellulose pyrolysis[J]. J Fuel Chem Technol, 2006, 34(2): 179-183.)

    22. [22] GLINSKI M, KIJENSKI J, JAKUBOWSKI A. Ketones from monocarboxylic acids: Catalytic ketonization over oxidesystems[J]. Appl Catal A: Gen, 1995, 128(2): 209-217.[22] GLINSKI M, KIJENSKI J, JAKUBOWSKI A. Ketones from monocarboxylic acids: Catalytic ketonization over oxidesystems[J]. Appl Catal A: Gen, 1995, 128(2): 209-217.

    23. [23] CRUZ-CABEZA A J, ESQUIVEL D, JIMENEZ-SANCHIDRIAN C, ROMERO-SALGUERO F J. Metal-exchanged β zeolites as catalysts for the conversion of acetone to hydrocarbons[J]. Materials, 2012, 5(1): 121-134.[23] CRUZ-CABEZA A J, ESQUIVEL D, JIMENEZ-SANCHIDRIAN C, ROMERO-SALGUERO F J. Metal-exchanged β zeolites as catalysts for the conversion of acetone to hydrocarbons[J]. Materials, 2012, 5(1): 121-134.

    24. [24] WANG S R, CAI Q J, WANG X Y, ZHANG L, WANG Y R, LUO Z Y. Biogasoline production from the Co-cracking of the distilled fraction of bio-oil and ethanol[J]. Energy Fuels, 2013, 28(1): 115-122.[24] WANG S R, CAI Q J, WANG X Y, ZHANG L, WANG Y R, LUO Z Y. Biogasoline production from the Co-cracking of the distilled fraction of bio-oil and ethanol[J]. Energy Fuels, 2013, 28(1): 115-122.

    25. [25] 郭祚刚. 基于分子蒸馏技术的生物油分级品位提升研究[D]. 杭州: 浙江大学, 2012.(GUO Zuo-gang. Bio-oil multiple upgrading research based on molecular distillation technology[D]. Hangzhou: Zhejiang University, 2012.)[25] 郭祚刚. 基于分子蒸馏技术的生物油分级品位提升研究[D]. 杭州: 浙江大学, 2012.(GUO Zuo-gang. Bio-oil multiple upgrading research based on molecular distillation technology[D]. Hangzhou: Zhejiang University, 2012.)

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  • 收稿日期:  2014-08-22
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